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Monel K500 Hex Head Bolt, UNS N05500/2.4375, 140-315 HB

Monel K500 Hex Head Bolt

QS Fastener: Monel K500 Hex Head Bolt
Name: Monel K500 Hex Head Bolt
Material: Monel K500, UNS N05500/2.4375
Hardness: 140 to 315 HB
Size: M30
Length: 50 mm
Application: For strong acid, strong alkali and high temperature, high pressure
Feature: nonmagnetic, high strength, corrosion resistance
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Monel K500 Hex Head Bolt is manufactured from a special nickel-copper alloy, with specifications such as M30×50mm and hardness ranging 140-315HB. Combining non-magnetic properties, ultra-high strength, and exceptional corrosion resistance, it is specifically designed for extreme environments involving strong acids/alkalis, high temperature, and high pressure. As a premium fastener, it is the preferred choice for critical equipment in petrochemical, seawater desalination, and nuclear industries.  
 
1. High-Temperature Oxidation Mechanism of Monel K500 Hex Head Bolt  
The high-temperature resistance of Monel K500 Hex Head Bolt stems from the synergistic effect of its Ni-Cu matrix and γ' (Ni₃(Al,Ti)) precipitates. However, at temperatures exceeding 480°C, performance degradation occurs due to:  
- γ' Phase Coarsening: Ni₃(Al,Ti) particles agglomerate and grow, reducing precipitation strengthening.  
- Oxide Layer Evolution: A NiO-dominant oxide film forms, but Cu migration causes localized oxide film fracture.  
 
2. Temperature-Dependent Performance Data of Monel K500 Hex Head Bolt 
Temperature RangeMechanical Property ChangesOxidation RateMicrostructural Evolution
-200°C to 200°CStrength retention >95%, no impact toughness loss (ASTM E23 cryogenic impact test)Negligible (stable oxide film) No γ' coarsening; dislocation motion restricted
200°C to 480°CTensile strength reduction ≤10% (aged: 1200MPa → 1080MPa @480°C/1000h)0.002–0.005 mm/year (ASTM G54)γ' growth <20nm (TEM observation)
480°C to 600°CTensile strength drops 30–40% (1200MPa → 720MPa @600°C/100h) 0.01–0.03 mm/year (oxide spalling)γ' size >50nm; Cu segregation at grain boundaries (EDS)
>600°C (short-term)Instantaneous strength maintained (e.g., Rm ≥850MPa @600°C/1h), but creep life <100h @650°C/200MPaRapid oxidation (>0.05 mm/year)γ' dissolution; Ni-Cu-Al-Ti eutectic formation (SEM)
 
3. High-Temperature Oxidation Kinetics of Monel K500 Hex Head Bolt 
- Oxidation Weight Gain (ASTM G76):  
  - 480°C/1000h: 0.8–1.2 mg/cm² (dense NiO + minor Cu₂O).  
  - 600°C/100h: 3.5–5.0 mg/cm² (stratified oxide film: inner NiO, outer CuO-rich).  

 
- Oxide Composition (XPS Analysis):  
  - <400°C: >90% NiO + trace Al₂O₃ (protective).  
  - >480°C: 70% NiO + 25% CuO + 5% TiO₂ (CuO increases brittleness).  
 
4. High-Temperature Performance Comparison of Monel K500 Hex Head Bolt vs. Competitors  
MaterialLong-Term Service Limit600°C Tensile Strength RetentionOxidation Rate @600°C (mm/year)
Monel K500 Hex Head Bolt480°C60–65%0.03–0.05
Inconel 718700°C85–90%0.01–0.02
316 Stainless Steel400°C40–50%0.10–0.15
 
Key Takeaways:  
- Inconel 718 outperforms Monel K500 Hex Head Bolt at higher temperatures due to γ'' (Ni₃Nb) phase stability (enhanced by Nb/Mo).  
- Monel K500 Hex Head Bolt offers superior cost-performance in 400–480°C ranges, especially where corrosion resistance + moderate heat resistance are required.  
 
5. High-Temperature Service Recommendations for Monel K500 Hex Head Bolt
(1) Temperature Control  
- Continuous Use: ≤450°C (strength retention >90%).  
- Short-Term Peak: ≤600°C for <50h (prevents irreversible γ' coarsening).  
 
(2) Environmental Suitability  
- Sulfur-Containing Atmospheres: >300°C may cause sulfidation corrosion (Ni₃S₂ formation; embrittlement threshold: 280°C).  
- Oxidizing-Reducing Cycling: Aluminized coating recommended (extends oxidation resistance to 800°C).  
 
6. Conclusion  
The 480°C long-term service limit of Monel K500 Hex Head Bolt is determined by γ' phase stability and oxide film protection. While it ranks among the top high-temperature nickel-copper alloys, prolonged load-bearing above 500°C must be avoided. For higher-temperature applications (e.g., jet engines), Inconel 718 or Waspaloy (Nb/Ti-strengthened alloys) are preferable alternatives.  

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